Ruthenium-Catalyzed Oxidative C(sp(2))-H Bond Hydroxylation: Site-Selective C-O Bond Formation on Benzamides

Thirunavukkarasu, Vedhagiri S.Vedhagiri S.ThirunavukkarasuHubrich, JonathanJonathanHubrichAckermann, LutzLutzAckermann2018-11-072018-11-072012https://resolver.sub.uni-goettingen.de/purl?gro-2/25729Well-defined ruthenium carboxylate complexes enabled unprecedented ruthenium-catalyzed C(sp(2))-H hydroxylations on benzamides with PhI(OAc)(2) as the oxidant at a remarkably low catalyst loading of 1.0 mol %.Ruthenium-Catalyzed Oxidative C(sp(2))-H Bond Hydroxylation: Site-Selective C-O Bond Formation on Benzamidesjournal_article10.1021/ol301881922853552000307526900045