Synthesis of the first compound with a rhombohedral Ti-6(mu(3)-NH)(6)(mu(3)-N)(2) core structure by ammonolysis of a titanium chelate in a two-phase system

Bai, G. C.G. C.BaiRoesky, H. W.H. W.RoeskyNoltemeyer, M.M.NoltemeyerHao, H. J.H. J.HaoSchmidt, H. G.H. G.Schmidt2018-11-072018-11-072000https://resolver.sub.uni-goettingen.de/purl?gro-2/46000Reaction of [{p-MeC6H4C(NSiMe3)(2)}(2)TiCl2] (1) with NaNH2 gave the novel titanium aggregate [{p-MeC6H4C(NSiMe3)(2)Ti}(6)(mu(3)-NH)(6)(mu(3)-N)(2). 6C(7)H(8)] (2). Treatment of 1 with potassium in liquid ammonia and toluene produced the titanium(III) complex [{p-MeC6H4C(NSiMe3)(2)}(3)Ti] (3). Compound 2 contains the largest Ti-N core so far reported.Synthesis of the first compound with a rhombohedral Ti-6(mu(3)-NH)(6)(mu(3)-N)(2) core structure by ammonolysis of a titanium chelate in a two-phase systemjournal_article10.1021/om0001927000088374300001