Bhaduri, SumitSumitBhaduriGopalkrishnan, Kalpathi S.Kalpathi S.GopalkrishnanClegg, WilliamWilliamCleggJones, Peter G.Peter G.JonesSheldrick, George M.George M.SheldrickStalke, DietmarDietmarStalke2009-06-112021-10-272009-06-112021-10-271984https://resolver.sub.uni-goettingen.de/purl?gro-2/91669Ru3(CO)10(NPh)](1) reacts with molecular hydrogen to give [Ru3H2(CO)9(NPh)](2), which can be carbonylated to produce [Ru3(CO)12]. A single-crystal X-ray structure determination of (2) confirms the presence of a triply-bridging NPh group and two doubly-bridging hydrogen atoms: space group P21/c, a= 11.697(2), b= 9.265(2), c= 18.589(4)Å, = 100.18(2)°, Z= 4, R= 0.039 for 3 019 unique observed reflections. Mean bond lengths include Ru–Ru 2.805(1)(H-bridged), 2.680(1)(unbridged), Ru–N 2.068(6), Ru–H 1.76(5)Å.application/pdfenGoescholarhttps://goescholar.uni-goettingen.de/licenseanorganische Chemie540journal_article10.1039/DT9840001765https://resolver.sub.uni-goettingen.de/purl?goescholar/3264openAccess