C-H Alkylations of (Hetero)Arenes by Maleimides and Maleate Esters through Cobalt(III) Catalysis

Zhang, Z.Z.ZhangHan, ShengnanShengnanHanTang, MengyaoMengyaoTangAckermann, LutzLutzAckermannLi, JieJieLi2018-11-072018-11-072017https://resolver.sub.uni-goettingen.de/purl?gro-2/42314Efficient cobalt(III)-catalyzed (hetero)aryl and alkenyl C-H hydroarylations of maleimides and maleate esters have been achieved under remarkably mild reaction conditions. Thus, the versatile cobalt(III) catalyst [Cp CoI2(CO)] showed excellent atom-and step-economy as well as high chemo- and site-selectivity providing expedient access to pharmacologically useful succinimides with wide functional group tolerance.C-H Alkylations of (Hetero)Arenes by Maleimides and Maleate Esters through Cobalt(III) Catalysisjournal_article10.1021/acs.orglett.7b0148028590740000403854300070