Ganapathy, DhandapaniDhandapaniGanapathyReiner, Johannes R.Johannes R.ReinerValdomir, GuillermoGuillermoValdomirSenthilkumar, SoundararasuSoundararasuSenthilkumarTietze, Lutz FriedjanLutz FriedjanTietze2018-11-072018-11-072017https://resolver.sub.uni-goettingen.de/purl?gro-2/43314The first enantioselective total synthesis of natural dicerandrol C (1c) as its enantiomer containing a dimeric tetrahydroxanthenone skeleton is described starting from the enantiopure chromane 6 which was obtained through a Wacker-type cyclization with >99%ee. For the formation of the dimeric skeleton a palladium-catalyzed Suzuki reaction was used. The synthesis allowed the confirmation of the absolute configuration of the dicerandrols.journal_article10.1002/chem.20170002028120501000395583200012