Singh, S.S.SinghJancik, V.V.JancikRoesky, H. W.H. W.RoeskyHerbst-Irmer, R.R.Herbst-Irmer2018-11-072018-11-072006https://resolver.sub.uni-goettingen.de/purl?gro-2/41535A monomeric hydroxide of gallium, LGa(Me)OH, containing terminal hydroxide and methyl groups was prepared by the hydrolysis of LGa(Me)Cl in the presence of N-heterocyclic carbene and water [L = HC{(CMe)(2,6-i-Pr2C6H3N)}(2)] in high yield and in a pure form. LGa(Me)OH was used as a synthon to assemble the first hetero-bimetallic compound with a Ga-O-Zr core, [(LGaMe)-(Cp2ZrMe)](u-O).Synthesis, characterization, and X-ray crystal structure of a gallium monohydroxide and a hetero-bimetallic gallium zirconium oxidejournal_article10.1021/ic051769l16441096000235198400002