Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C-H Bond Cleavages with Sulfamates or Phosphates as Electrophiles

Ackermann, LutzLutzAckermannBarfuesser, SebastianSebastianBarfuesserPospech, JolaJolaPospech2018-11-072018-11-072010https://resolver.sub.uni-goettingen.de/purl?gro-2/20551A catalytic system comprised of Pd(OAc)(2) and bidentate ligand dppe enabled first direct arylations with moisture-stable aryl sulfamates as electrophiles, and proved applicable to unprecedented C-H bond functionalizations with easily accessible alkenyl phosphates as well as benzyl phosphates.Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C-H Bond Cleavages with Sulfamates or Phosphates as Electrophilesjournal_article10.1021/ol902803420078115000274465900020