Publication: Efficient synthesis of ortho-carborane by reaction of propiolic acid tert-butyl ester with decaborane(14)
| dc.bibliographiccitation.firstpage | 1109 | |
| dc.bibliographiccitation.issue | 7 | |
| dc.bibliographiccitation.journal | Synlett | |
| dc.bibliographiccitation.lastpage | 1110 | |
| dc.contributor.author | Tietze, Lutz Friedjan | |
| dc.contributor.author | Griesbach, U. | |
| dc.contributor.author | Elsner, O. | |
| dc.date.accessioned | 2018-11-07T10:24:14Z | |
| dc.date.available | 2018-11-07T10:24:14Z | |
| dc.date.issued | 2002 | |
| dc.description.abstract | Reaction of propiolic acid tert-butyl ester I and decaborane(14) at 90 degreesC did not give the expected carborane carboxylic acid tert-butyl ester 3 but directly unsubstituted ortho-carborane 2 which was isolated in 52% yield as pure material, An in situ de-tert-butoxycarbonylation of the first formed carborane carboxylic acid tert-butyl ester 3 via a six membered transition state is suggested for this domino process. | |
| dc.identifier.isi | 000176746900017 | |
| dc.identifier.uri | https://resolver.sub.uni-goettingen.de/purl?gro-2/42618 | |
| dc.notes.status | zu prüfen | |
| dc.notes.submitter | Najko | |
| dc.publisher | Georg Thieme Verlag Kg | |
| dc.relation.issn | 0936-5214 | |
| dc.title | Efficient synthesis of ortho-carborane by reaction of propiolic acid tert-butyl ester with decaborane(14) | |
| dc.type | journal_article | |
| dc.type.internalPublication | yes | |
| dc.type.peerReviewed | yes | |
| dc.type.status | published | |
| dspace.entity.type | Publication |