Publication:
Phase Behaviour of CoCl2-MnCl2 Mixed Crystals

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dc.bibliographiccitation.firstpage413
dc.bibliographiccitation.issue4
dc.bibliographiccitation.journalZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
dc.bibliographiccitation.lastpage419
dc.bibliographiccitation.volume225
dc.contributor.authorDavaasambuu, Jav
dc.contributor.authorGuethoff, Friedrich
dc.contributor.authorHoelzel, Markus
dc.contributor.authorSenyshyn, Anatoliy
dc.contributor.authorRadulescu, Aurel
dc.contributor.authorEckold, Goetz
dc.date.accessioned2018-11-07T09:02:06Z
dc.date.available2018-11-07T09:02:06Z
dc.date.issued2011
dc.description.abstractThermal properties of CoCl2, MnCl2 and their mixed crystals are investigated by means of temperature dependent neutron powder diffraction and time-resolved small angle neutron scattering. The coefficients of thermal expansion of these crystals have been determined as a function of temperature. The temperature-induced structural variations can be explained by distortions of CoCl5/MnCl6 octahedra and changes in Co/Mn-Cl bond lengths. CoCl2 and MnCl2 form homogeneous solid solutions in the entire temperature range between the solidus and 50 K. There is no indication of any miscibility gap as predicted from thermodynamic calculations.
dc.description.sponsorshipDFG [EC 153/3-1]
dc.identifier.doi10.1524/zpch.2011.0115
dc.identifier.isi000290690700003
dc.identifier.urihttps://resolver.sub.uni-goettingen.de/purl?gro-2/24599
dc.notes.statuszu prüfen
dc.notes.submitterNajko
dc.publisherOldenbourg Verlag
dc.relation.issn0942-9352
dc.titlePhase Behaviour of CoCl2-MnCl2 Mixed Crystals
dc.typejournal_article
dc.type.internalPublicationyes
dc.type.peerReviewedyes
dc.type.statuspublished
dspace.entity.typePublication

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