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sigma/pi versus pi/pi Conjugation: DFT Studies on Oligocyclopropenones and Related Systems

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dc.bibliographiccitation.firstpage5231
dc.bibliographiccitation.issue22
dc.bibliographiccitation.journalOrganic Letters
dc.bibliographiccitation.lastpage5234
dc.bibliographiccitation.volume10
dc.contributor.authorWerz, Daniel B.
dc.contributor.authorDuefert, Alexander
dc.date.accessioned2018-11-07T11:08:59Z
dc.date.available2018-11-07T11:08:59Z
dc.date.issued2008
dc.description.abstractDFT studies on oligocyclopropenones and related systems 5(n)-9(n) are reported. A strong sigma/pi interaction between the pi system and the or framework of the three-membered rings is observed in almost all cases, leading to a perpendicular arrangement of the pi systems in the most favored conformation. Also the shape of cyclic congeners is strongly influenced by sigma/pi interactions.
dc.identifier.doi10.1021/ol8022566
dc.identifier.isi000260922500034
dc.identifier.pmid18954063
dc.identifier.urihttps://resolver.sub.uni-goettingen.de/purl?gro-2/52918
dc.notes.statuszu prüfen
dc.notes.submitterNajko
dc.publisherAmer Chemical Soc
dc.relation.issn1523-7060
dc.titlesigma/pi versus pi/pi Conjugation: DFT Studies on Oligocyclopropenones and Related Systems
dc.typejournal_article
dc.type.internalPublicationyes
dc.type.peerReviewedyes
dc.type.statuspublished
dspace.entity.typePublication

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