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Synthesis of the first compound with a rhombohedral Ti-6(mu(3)-NH)(6)(mu(3)-N)(2) core structure by ammonolysis of a titanium chelate in a two-phase system

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dc.bibliographiccitation.firstpage2823
dc.bibliographiccitation.issue15
dc.bibliographiccitation.journalOrganometallics
dc.bibliographiccitation.lastpage2825
dc.bibliographiccitation.volume19
dc.contributor.authorBai, G. C.
dc.contributor.authorRoesky, H. W.
dc.contributor.authorNoltemeyer, M.
dc.contributor.authorHao, H. J.
dc.contributor.authorSchmidt, H. G.
dc.date.accessioned2018-11-07T10:39:15Z
dc.date.available2018-11-07T10:39:15Z
dc.date.issued2000
dc.description.abstractReaction of [{p-MeC6H4C(NSiMe3)(2)}(2)TiCl2] (1) with NaNH2 gave the novel titanium aggregate [{p-MeC6H4C(NSiMe3)(2)Ti}(6)(mu(3)-NH)(6)(mu(3)-N)(2). 6C(7)H(8)] (2). Treatment of 1 with potassium in liquid ammonia and toluene produced the titanium(III) complex [{p-MeC6H4C(NSiMe3)(2)}(3)Ti] (3). Compound 2 contains the largest Ti-N core so far reported.
dc.identifier.doi10.1021/om0001927
dc.identifier.isi000088374300001
dc.identifier.urihttps://resolver.sub.uni-goettingen.de/purl?gro-2/46000
dc.notes.statuszu prüfen
dc.notes.submitterNajko
dc.publisherAmer Chemical Soc
dc.relation.issn0276-7333
dc.titleSynthesis of the first compound with a rhombohedral Ti-6(mu(3)-NH)(6)(mu(3)-N)(2) core structure by ammonolysis of a titanium chelate in a two-phase system
dc.typejournal_article
dc.type.internalPublicationyes
dc.type.peerReviewedyes
dc.type.statuspublished
dspace.entity.typePublication

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