Publication: A Dodecanuclear Copper(I) Complex Containing a Cubic (CuS)(4) Core Stabilized by a Tripodal (N,N,P)-Chelating Ligand
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Date
2011
Authors
Stalke, Dietmar
Journal Title
Journal ISSN
Volume Title
Publisher
Verlag Z Naturforsch
Abstract
We present the structure elucidation of a copper(I) complex of a monoanionic phosphanylalkyl-diimido sulfonate ligand centered by a sulfur-copper cube. It has the formula [{Me2PCH2S(NSiMe3)(2)}(4) Cu-8{CuS}(4)] (2) and is the first example of a copper(I) complex of this new ligand type.