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Photocatalytic Functionalization of Heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]Tetradecane

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dc.bibliographiccitation.artnumberadsc.202301323
dc.bibliographiccitation.journalAdvanced Synthesis & Catalysis
dc.contributor.authorRecort‐Fornals, Martí
dc.contributor.authorMarset, Xavier
dc.contributor.authorSimon, Martin
dc.contributor.authorGolz, Christopher
dc.contributor.authorRamón, Diego J.
dc.contributor.authorAlcarazo, Manuel
dc.date.accessioned2024-02-03T22:15:14Z
dc.date.available2024-02-03T22:15:14Z
dc.date.issued2023
dc.description.abstractAbstract The regioselective functionalization of heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]tetradecane (HCTD) under photocatalytic conditions is described. The protocols developed share an initial photo‐triggered hydrogen atom abstraction that regioselectively generates the necessary HCTD‐radical preferentially at position 1‐, they employ no excess of the precious cage carbocycle, and enable the straightforward access to a broad variety of 1‐(alkyl, aryl, or sulfinyl) HCTDs in moderate but still synthetically useful yields. The scope and limitations of each transformation are also discussed.
dc.description.sponsorshipGeneralitat Valenciana https://doi.org/10.13039/501100003359
dc.identifier.doi10.1002/adsc.202301323
dc.identifier.urihttps://resolver.sub.uni-goettingen.de/purl?gro-2/140276
dc.item.fulltextNo Fulltext
dc.language.isoen
dc.notes.internDOI-Import GROB-731
dc.notes.internGefördert über DFG OAPK
dc.relation.eissn1615-4169
dc.relation.issn1615-4150
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.titlePhotocatalytic Functionalization of Heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]Tetradecane
dc.typejournal_article
dc.type.internalPublicationyes
dspace.entity.typePublication

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