Publication:
Coordination Abilities of Di-2-picolylphenylphosphane Judged on the Basis of Charge Density Investigations

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dc.bibliographiccitation.firstpage2005
dc.bibliographiccitation.issue11
dc.bibliographiccitation.journalZeitschrift für anorganische und allgemeine Chemie
dc.bibliographiccitation.lastpage2012
dc.bibliographiccitation.volume639
dc.contributor.authorObjartel, Ina
dc.contributor.authorLeusser, Dirk
dc.contributor.authorEngelhardt, Felix
dc.contributor.authorHerbst-Irmer, Regine
dc.contributor.authorStalke, Dietmar
dc.date.accessioned2018-11-07T09:20:14Z
dc.date.available2018-11-07T09:20:14Z
dc.date.issued2013
dc.description.abstractThe hindered reactivity of [PhP(CH2Py)(2)LiCl](2) (2) compared to the coordination behavior of the lithium chloride free ligand PhP(CH2Py)(2) (Py = 2-pyridyl) (1) could be elucidated by means of experimental electron density studies. According to the successful synthesis of metal complexes containing the dianionic Janus Head ligand [PhP(CHPy)(2)](2-), the formation and the coordination pattern of the monoanionic ligand [PhP{C(H)Py}(CH2Py)](-) was examined. The reaction of ligand 1 with n-butyllithium/PMDETA and the superbase n-butyllithium/NaOtBu, respectively, led to the alkali metal complexes [(PMDETA)Li{C(H)Py}P(CH2Py)Ph] (5) and [(PyCH2)PhP{C(H)Py}Na(Et2O)](2) (6).
dc.identifier.doi10.1002/zaac.201300092
dc.identifier.isi000327820400012
dc.identifier.urihttps://resolver.sub.uni-goettingen.de/purl?gro-2/28839
dc.notes.statuszu prüfen
dc.notes.submitterNajko
dc.publisherWiley-v C H Verlag Gmbh
dc.relation.issn1521-3749
dc.relation.issn0044-2313
dc.titleCoordination Abilities of Di-2-picolylphenylphosphane Judged on the Basis of Charge Density Investigations
dc.typejournal_article
dc.type.internalPublicationyes
dc.type.peerReviewedyes
dc.type.statuspublished
dspace.entity.typePublication

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